PRODUCT SAFETY DATA SHEET

Ref: 2K 5:1 320 PRIMER Date: 05.09.11 Page: 1 01. IDENTIFICATION OF SUBSTANCE / PREPARATIONS:

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Product name: Product code: Description: Supplier:

2K 5:1 320 PRIMER

P32G25, P32G50, P32G80

320 GREY PRIMER

MB Products (UK) Ltd, t/a MB Coatings

Unit 230 Ampress Business Park

Lymington

Hants SO41 8JW

Tel: 01590 677676 Fax: 01590 678578. Website: www.mbcoatings.co.uk________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________

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02. COMPOSITION / INFORMATION ON INGREDIENTS:

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Description

Ethylbenzene 2-Methoxy-1- methylethyl Acetate N-Butyl Acetate Xylene

CAS no.

100-41-4 108-65-6

123-86-4

EINECS no.

202-849-4 203-603-9

204-658-1

% (weight)

1-2 <1,0

– Vapours may cause drowsiness and dizziness.________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________

04. First Aid Measures:
General
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to

an unconscious person.

Inhalation

Remove patient to fresh air and seek medical assistance. If breathing is irregular or stopped, administer artificial respiration. Give nothing by mouth. If unconscious place in recover position.
Skin Contact
Remove contaminated clothing. Wash skin with soap and water, rinse abundantly.

Eye Contact

Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 15 minutes,

holding the eyelids apart and seek medical advice.

Ingestion

Immediately rinse mouth and then drink plenty of water. Do NOT induce vomiting. Keep the patient warm

and at rest and call a doctor immediately.________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________

05. Fire-Fighting Measures:
Suitable Extinguishing Media
CO2 Foam, chemical powder for flammable liquids. Water may not be used to extinguish fire but it should be used to cool the containers exposed to flames and prevent fires and explosions. For leakage and spillage

Symbol

F, Xn

03. Hazards Identification:

Xn- Harmful Flammable

Risk Warnings

  • –  Flammable.
  • –  May cause sensitization by skin contact.

Classification

R11, R20 R10

R10, R66,R67

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1330-20-7

215-535-7

8-10
12,0 – 13,0

Xn, Xi ________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________

R10, R20/21, R38

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The texts of the R phases are listed in chapter 16.

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PRODUCT SAFETY DATA SHEET

Ref: 2K 5:1 320 PRIMER Date: 05.09.11 Page: 2

that have not could fire nebulized water may be used to disperse flammable vapours. Do not allow run-off from fire fighting to enter drains or watercourses.
Unsuitable Extinguishing Method
Water Jet

Special Hazards due to the Substance, its Decomposition Products or Gases products by Fire:

Fire will produce dense black smoke. Inhalation of dangerous decomposition products may cause serious damage to health.
Special Protective Equipment
Appropriate breathing apparatus, helmet with face shield, protection for neck may be required.

Addition information

Cool closed containers in the vicinity of the source of fire.________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________

06. Accidental Release Measures:

Person Protective Measures

Refer to protective measures listed in sections 5.

Exclude sources of ignition and ventilate the area. Avoid breathing vapours.

Measures to Protect the Environment

Do not allow to enter drains or watercourses. If the product enters drains or sewers, the local water

company should be contacted immediately; in the case of contamination of streams, rivers or lakes the

Environment Agency.

Cleaning Measures

Contain and collect spillage with non-combustible absorbent materials e.g. sand, earth, vermiculite,

diatomaceous earth and place in a suitable container for disposal according with the waste regulations (see

section 13). Clean preferably with a detergent; avoid the use of solvents.________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________

07. Handling and Storage:
Handling
Instructions for Safe Handling
Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentration higher than the occupational exposure limits.

Avoid skin and eye contact. Avoid inhalation of vapour.
Smoking, eating and drinking are forbidden in application area. For personal protection see section 8. Comply with the Health and Safety at work laws.
Isolate from sources of heat, sparks and open flame. Do not use any sparking tools
Product may charge electrostatically: always use earthing leads when transferring from one container to another and earth containers. It is recommended that operators should wear anti-static clothing and footwear.
Information on Fire and Explosion Protection
Solvent vapors are heavier than air and spread along floors.
Vapor forms explosive mixtures with air.
Keep container dry and tightly closed in a cool well-ventilated place.
Storage
Requirements for Storage Areas and Containers
Electrical equipment must be explosion-proof to the appropriate standard. Floors must be conducting type and impermeable to the materials being stored.
Keep container tightly closed. Never use pressure to empty; container is not a pressure vessel. Close containers carefully once opened and store upright in order to prevent any leakage. No smoking. Prevent unauthorized access.
Additional Information on Storage Conditions
Always keep in containers of the same material as the original one.
Observe label precautions. Store in a well-ventilated place away from sources of heat and direct sunlight. Keep away from sources of ignition.
Specific use(s)

Detailed information can be gained from the relevant technical data sheets.____________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________

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PRODUCT SAFETY DATA SHEET
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08. Exposure Controls / Personal Protection
Engineering Measures
Provide adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations at the work place below the occupational exposure limits, appropriate certified respirators must be worn.
Exposure control / Personal protection

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Substance Name

2-Butoxyethanol
Xylene 2-Methoxy-1-methylethyl acetate Ethylbenzene

Personal Protection

Respiratory Protection

8hr LTEL ppm mg/m 3

20    98
50    221
50    275
100    442

15min STEL ppm mg/m3 50 276 100 442 100 550 200 884

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When workers are facing concentrations above the occupational exposure limited they must use appropriate

certified respirators, goggles and overalls.

Hand Protection

Wear protective gloves.

Any chemical protection glove certified according to EN 374 is suitable: e.g. nitrile gloves. Material

thickness: 1,25 mm

The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use

preventative skin protection (skin cream).

Eye Protection

Required when there is a risk of eye contact.

Use tight-fitting protective goggles.

Environmental exposure controls

See section 7 and 12 ________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________

09 Physical and Chemicals Properties

Physical state
Colour
Odour
Specific gravity
Flammable
Explosive properties: Limits Oxidizing properties

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: Liquid
: Grey
: Typical of Solvents
: ca 1.58g/cm3
: High viscosity liquid, flammable
: Not explosive, no concern
: Not Oxidizing, no concern
: Rotational rheometer 5000-8000mpas

Stable under recommended storage and handling conditions (see section 7)

Conditions to be avoided

Substances to be avoided

Keep away from highly acidic or alkaline substances as well as oxidants in order to prevent exothermal

reactions.

Hazardous Decomposition Products

When exposed to high temperatures may produce hazardous decomposition products such as carbon

monoxide, carbon dioxide, smoke, oxides of nitrogen.________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________

11. Toxicological Information

Exposure to component solvent vapor concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as serious depression of the central nervous system, symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Toluene has a toxic effect on the central and peripheral nervous system (with encephalopathies and polyneuritis), irritating to the skin, conjunctivae, cornea and respiratory apparatus. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact

Other properties: viscosity________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________

10. Stability and Reactivity

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PRODUCT SAFETY DATA SHEET

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dermatitis and absorption through the skin.

The liquid splashed in the eyes may cause irritation and reversible damage.________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________

12. Ecological Information

General

There are no test results available for this product.

The preparation has been assessed following the conventional method of the Dangerous Preparations

Directive 1999/45/EC and is classified for eco-toxicological properties accordingly. See sections 2 and 15

for details.

The product should not be allowed to enter drains or watercourses. If the product enters drains or sewers,

the local water company should be contacted immediately; in the case of contamination of streams, rivers

or lakes the Environment Agency________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________

13. Disposal Considerations

Consider the possibility of burning the product in a suitable incinerator. Acid or basic products must always be neutralized before undergoing any treating including biological treatment whenever feasible. If the waste is solid it can be disposed of in a landfill.
Dirty Containers

Recommendation

Containers which are not properly emptied must be disposed pursuant to Directive 91/689/EEC.________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________

14. Transport Information

Transport by Road or Rail – UN 1263, Paint, Class 3, Packing Group III, Hazardous identification

number 30. Marine Pollutant: NO

Sea Transport – UN 1263, Paint, Class 3, Packing Group III, EmS Code: F-E, S-E, Marine Pollutant: NO

Air Transport IATA – UN 1263, Paint, Class 3, Packing Group III, Marine Pollutant: NO________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________

15. Regulatory Information

Xn-Harmful

Risk Warnings;

Danger labeling under regulations 67/548/EEC and 1999/45/EC and following amendments and

adjustments.

Workers exposed to this chemical agent must not undergo health checks, providing that available risk-

assessment data prove that the risks related to the worker’s health and safety are modest and that the

98/24EC regulation is respected.
_____________________________________________________________________________________________________________________________ ___________________________________________________________________________________________________________________________________________________________________

16. Other Information

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Restricted to professional users.
Full text of risk warnings for components listed in section 2 R Phases
R10 :
R11 :
R20/21 :
R38 :
R66 :
R6 :
H-Phrases
H225
H226
H312
H315

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Flammable.
Highly Flammable.
Harmful by inhalation and in contact with skin. Irritation to skin.
Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness.

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: : : :

Highly flammable liquid and vapour. Flammable liquid and vapour. Harmful in contact with skin
Causes skin irritation.

Ref: H332 : H336 :

P Phrases
P102 : P260 : P271 : P280 : P304 + P340 :

P312 :

EUH 066 :

Acute Toxic 4 :

Flammable Liquid 2:

Flammable Liquid 3:

PRODUCT SAFETY DATA SHEET

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Harmful in inhaled.
May cause drowsiness or dizziness.

Keep locked up and out of reach of children. Do not breathe gas/fumes/vapor/spray.
Use only in well-ventilated areas.
Wear suitable protective clothing

If Inhale: Remove to fresh air and keep at rest in a position comfortable for breathing.
Call a Poison Center or Doctor/Physician if you fell unwell
Repeated exposure may cause skin dryness or cracking.

Acute toxicity, category 4 Flammable liquids, category 2

Flammable liquids, category 3

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Skin Irritation : Irritating for skin category 2

STOT SE3 : Specific target organ toxicity single exposure, category 3

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The information of this Safety Data Sheet is based on the present state of our knowledge and on current EU and national laws. The product is not to be used for other purposes than those specified under section 1 without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this SDS is meant as a description of the safety requirements of our product: it is not to be considered as a guarantee of the products` properties.